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reaction: see text]. Chiral 1,5-diaza-cis-decalins have been examined as ligands in the enantioselective oxidative biaryl coupling of substituted 2-naphthol derivatives. Under the optimal conditions employing a 1,5-diaza-cis-decalin copper(I) iodide complex with oxygen as the oxidant, rapid and highly selective couplings could be achieved (90-93% ee, 85% yield).

Citation

X Li, J Yang, M C Kozlowski. Enantioselective oxidative biaryl coupling reactions catalyzed by 1,5-diazadecalin metal complexes. Organic letters. 2001 Apr 19;3(8):1137-40

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PMID: 11348178

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