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A facile direct synthesis of cinnamonitriles from acrylonitriles and benzenes is successfully achieved by using Pd(OAc)(2)/HPMoV/O(2) catalyst system via the direct C-H bond activation of benzenes using molecular oxygen as a terminal oxidant.

Citation

Yasushi Obora, Yoshihisa Okabe, Yasutaka Ishii. Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)(2)/HPMoV/O(2) system. Organic & biomolecular chemistry. 2010 Sep 21;8(18):4071-3

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PMID: 20652185

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