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An efficient single-enzymatic cascade approach for the asymmetric synthesis of chiral amines has been developed, which applies the amino donor 3-aminocyclohexa-1,5-dienecarboxylic acid spontaneously tautomerizing to reach reaction completion with excellent ee values.

Citation

Bo Wang, Henrik Land, Per Berglund. An efficient single-enzymatic cascade for asymmetric synthesis of chiral amines catalyzed by ω-transaminase. Chemical communications (Cambridge, England). 2013 Jan 7;49(2):161-3

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PMID: 23169388

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