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    The development of rhodium-catalyzed diastereoselective N-sulfonylaminoalkenylation of azulenes using N-sulfonyltriazoles is described. This procedure can be successfully applied to rhodium-catalyzed diastereoselective N-sulfonylaminoalkenylation of azulenes starting from terminal alkynes and N-sulfonylazides via a three-component semi-one-pot process.

    Citation

    Sangjune Park, Woo-Soon Yong, Sanghyuck Kim, Phil Ho Lee. Diastereoselective N-sulfonylaminoalkenylation of azulenes from terminal alkynes and azides via N-sulfonyl-1,2,3-triazoles. Organic letters. 2014 Sep 5;16(17):4468-71

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    PMID: 25133587

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