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We report on the permeation of free and macrocycle-bound avobenzone across a POPC lipid bilayer through combined neutron reflectometry experiments and molecular dynamics simulations. Results indicate that the p-phosphonated calix[8]arene macrocycle limits the avobenzone penetration into the upper leaflet of the membrane. Hence, it could serve as a useful vehicle for safer formulations. This journal is © The Royal Society of Chemistry.

Citation

Harshita Kumari, Andrew Eisenhart, Jinnipha Pajoubpong, Frank Heinrich, Thomas L Beck. Investigating partitioning of free versus macrocycle bound guest into a model POPC lipid bilayer. RSC advances. 2020 Apr 16;10(26):15148-15153


PMID: 35495443

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