Amarisolide monohydrate, a 2-(beta-glucosyl)neoclerodane.
R A Toscano, E Maldonado, A Ortega, J Cárdenas
Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, Apartado Postal 70-213, México DF 04510, México. toscano@servidor.unam.mx
Acta crystallographica. Section C, Crystal structure communications 2001 JulThe absolute configuration of the neoclerodane glycoside amarisolide, presented here as the monohydrate, C26H36O9*H2O, has been determined by association with the known configuration of the glucose moiety. Its structure was established as 2beta-(O-beta-D-glucopyranosyl)neocleroda-3,13(16),14-trien-15,16-epoxy-18,19-olide. Extensive hydrogen bonding among the hydroxyl groups of the sugar moiety forms layers which are interconnected by water molecules.
Citation
R A Toscano, E Maldonado, A Ortega, J Cárdenas. Amarisolide monohydrate, a 2-(beta-glucosyl)neoclerodane. Acta crystallographica. Section C, Crystal structure communications. 2001 Jul;57(Pt 7):846-7
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PMID: 11443262
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