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Efficient amination of sulfides with a ketomalonate-derived oxaziridine: application to [2,3]-sigmatropic rearrangements of allylic sulfimides.
Alan Armstrong, Richard S Cooke
Department of Chemistry, Imperial College, London, UK SW7 2AY. A.Armstrong@ic.ac.uk
Chemical communications (Cambridge, England) 2002 Apr 21Sizes of these terms reflect their relevance to your search.
A novel N-Boc-oxaziridine is reported, derived from diethyl ketomalonate, which effects efficient amination of sulfides to sulfimides. The reagent is applied to the [2,3]-sigmatropic rearrangement of allylic sulfimides.
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Alan Armstrong, Richard S Cooke. Efficient amination of sulfides with a ketomalonate-derived oxaziridine: application to [2,3]-sigmatropic rearrangements of allylic sulfimides. Chemical communications (Cambridge, England). 2002 Apr 21(8):904-5
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PMID: 12123037
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