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Amination and [2,3]-sigmatropic rearrangement of propargylic sulfides using a ketomalonate-derived oxaziridine: synthesis of N-allenylsulfenimides.
Alan Armstrong, Richard S Cooke, Stephen E Shanahan
Department of Chemistry, Imperial College London, South Kensington, London, UK. A.Armstrong@imperial.ac.uk
Organic & biomolecular chemistry 2003 Sep 21Sizes of these terms reflect their relevance to your search.
Amination of propargylic sulfides with a ketomalonate-derived oxaziridine under metal free conditions gives N-Boc-N-allenylsulfenimides via [2,3]-sigmatropic rearrangement.
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Alan Armstrong, Richard S Cooke, Stephen E Shanahan. Amination and [2,3]-sigmatropic rearrangement of propargylic sulfides using a ketomalonate-derived oxaziridine: synthesis of N-allenylsulfenimides. Organic & biomolecular chemistry. 2003 Sep 21;1(18):3142-3
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PMID: 14527143
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