Fast, long-range electron-transfer reactions of a "blue" copper protein coupled non-covalently to an electrode through a stilbenyl thiolate monolayer.

Fraser A Armstrong, Nicola L Barlow, Paul L Burn, Kevin R Hoke, Lars J C Jeuken, Catherine Shenton, Graham R Webster

Chemical communications (Cambridge, England) 2004 Feb 07

filter terms:

A self-assembled monolayer (SAM), formed by the insitu saponification of a stilbenyl thioacetate on a gold electrode, yields fast electron transfer (ET)(the exchange rate at zero driving force exceeds 1600 s-1) with adsorbed molecules of the blue copper protein, azurin, over a distance exceeding 15 angstroms .

Citation

Fraser A Armstrong, Nicola L Barlow, Paul L Burn, Kevin R Hoke, Lars J C Jeuken, Catherine Shenton, Graham R Webster. Fast, long-range electron-transfer reactions of a "blue" copper protein coupled non-covalently to an electrode through a stilbenyl thiolate monolayer. Chemical communications (Cambridge, England). 2004 Feb 07(3):316-7