Unexpected formation of a novel macrocyclic tetraphosphine: (RSSR)-1,9-dibenzyl-3,7,11,15-tetramesityl-1,9-diaza-3,7,11,15-tetraphosphacyclohexadecane.

Roman N Naumov, Andrey A Karasik, Oleg G Sinyashin, Peter Lönnecke, Evamarie Hey-Hawkins

A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan Scientific Center, Arbuzov str. 8, Kazan, Russian Federation, 420088.

Dalton transactions (Cambridge, England : 2003) 2004 Feb 7

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The title compound was synthesised in moderate yield via stereoselective self-assembly of two bisphosphine, four formaldehyde and two primary amine molecules. Copyright 2004 The Royal Society of Chemistry

Citation

Roman N Naumov, Andrey A Karasik, Oleg G Sinyashin, Peter Lönnecke, Evamarie Hey-Hawkins. Unexpected formation of a novel macrocyclic tetraphosphine: (RSSR)-1,9-dibenzyl-3,7,11,15-tetramesityl-1,9-diaza-3,7,11,15-tetraphosphacyclohexadecane. Dalton transactions (Cambridge, England : 2003). 2004 Feb 7(3):357-8