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The first total synthesis of (-)-methyl barbascoate.
Hisahiro Hagiwara, Kenta Hamano, Masato Nozawa, Takashi Hoshi, Toshio Suzuki, Fusao Kido
Graduate School of Science and Technology, Niigata University, 8050, 2-Nocho, Ikarashi, Niigata 950-2181, Japan. hagiwara@gs.niigata-u.ac.jp
The Journal of organic chemistry 2005 Mar 18Sizes of these terms reflect their relevance to your search.
reaction: see text] The neo-trans-clerodane natural product, (-)-methyl barbascoate 1, has been synthesized for the first time starting from the known ketone 6 derived from (R)-(-)-Wieland-Miescher ketone analogue 5.
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Hisahiro Hagiwara, Kenta Hamano, Masato Nozawa, Takashi Hoshi, Toshio Suzuki, Fusao Kido. The first total synthesis of (-)-methyl barbascoate. The Journal of organic chemistry. 2005 Mar 18;70(6):2250-5
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PMID: 15760212
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