Dynamic helicity inversion in an octahedral cobalt(II) complex system via solvato-diastereomerism.

Hiroyuki Miyake, Hideki Sugimoto, Hitoshi Tamiaki, Hiroshi Tsukube

Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan. miyake@sci.osaka-cu.ac.jp

Chemical communications (Cambridge, England) 2005 Sep 14

filter terms:

The helical sense of a mononuclear Co(II) complex with an amino acid-based chiral tetradentate ligand was dynamically inverted by changing the solvent component.

Citation

Hiroyuki Miyake, Hideki Sugimoto, Hitoshi Tamiaki, Hiroshi Tsukube. Dynamic helicity inversion in an octahedral cobalt(II) complex system via solvato-diastereomerism. Chemical communications (Cambridge, England). 2005 Sep 14(34):4291-3