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The first synthetic route to amaminol A with use of an organocatalytic intramolecular Diels-Alder reaction is reported. The absolute stereochemistry is proven with a crystallographic image of a cyclic carbamate of amaminol A.

Citation

Esa T T Kumpulainen, Ari M P Koskinen, Kari Rissanen. Total synthesis of amaminol A: establishment of the absolute stereochemistry. Organic letters. 2007 Nov 22;9(24):5043-5

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PMID: 17956115

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