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Synthesis of poly(para-phenylene)(2-isocyano-2-tosylpropane-1,3-diyl), poly(para-phenylene)(2-oxopropane-1,3-diyl) and oligo(cyclopentadienones) via carbonylative coupling of alpha,alpha'-dibromoxylene.
Robert G Potter, Thomas S Hughes
Department of Chemistry, Cook Physical Sciences Building, University of Vermont, Burlington, VT 05401, USA.
Chemical communications (Cambridge, England) 2007 Nov 28Sizes of these terms reflect their relevance to your search.
Poly(para-phenylene)(2-oxopropane-1,3-diyl), a potential precursor of linear graphene, is generated in low yield from hydrolysis of a previously unknown poly(para-phenylene)(2-isocyano-2-tosylpropane-1,3-diyl) generated from inexpensive, commercially available starting materials.
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Robert G Potter, Thomas S Hughes. Synthesis of poly(para-phenylene)(2-isocyano-2-tosylpropane-1,3-diyl), poly(para-phenylene)(2-oxopropane-1,3-diyl) and oligo(cyclopentadienones) via carbonylative coupling of alpha,alpha'-dibromoxylene. Chemical communications (Cambridge, England). 2007 Nov 28(44):4665-7
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PMID: 17989826
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