Oxidation leading to reduction: redox-induced electron transfer (RIET).

Complex electron transfer reactions have been characterized whereby in addition to electron transfer, subsequent electrochemical, chemical and even in some cases biological consequences occur. These include a secondary electron transfer that leads to a major rearrangement of the electronic structure, such that an initial oxidation leads to a reduction (or an initial reduction leads to an oxidation) for these valence ambiguous compounds. Mixed valency and valence-tautomeric behaviors can additionally result from these complex electron-transfer-induced reactions.

Citation

Joel S Miller, Kil Sik Min. Oxidation leading to reduction: redox-induced electron transfer (RIET). Angewandte Chemie (International ed. in English). 2009;48(2):262-72

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PMID: 18972460

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