Mingcun Wang, Chunbao Charles Xu, Mathew Leitch
Department of Chemical Engineering, Lakehead University, Thunder Bay, ON, Canada.
Bioresource technology 2009 AprCornstalk powders were effectively liquefied in a hot-compressed phenol-water medium (1:4 wt/wt). The optimum liquefaction temperature was around 350 degrees C, where the liquid yield attained a maximum at about 70 wt%. The addition of sodium carbonate showed negligible effect over the Liquefaction product yields. When liquefied in phenol-water medium, essentially no phenol was combined with the liquid products, and the cornstalk-derived bio-oils were partially degraded monomeric and oligomeric products with a broad molecular distribution. Resol type bio-based phenol formaldehyde resins were readily synthesized from the cornstalk-derived bio-oils catalyzed by sodium hydroxide.
Mingcun Wang, Chunbao Charles Xu, Mathew Leitch. Liquefaction of cornstalk in hot-compressed phenol-water medium to phenolic feedstock for the synthesis of phenol-formaldehyde resin. Bioresource technology. 2009 Apr;100(7):2305-7
PMID: 19058960
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