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Bridgehead enolates and bridgehead alkenes in a welwistatin model series.
Valerie Boissel, Nigel S Simpkins, Gurdip Bhalay, Alexander J Blake, William Lewis
School of Chemistry, The University of Nottingham, University Park, Nottingham, UK NG7 2RD.
Chemical communications (Cambridge, England) 2009 Mar 21Sizes of these terms reflect their relevance to your search.
Bridgehead metallation is possible in a ketone having the welwistatin skeleton, and this facilitates installation of the isothiocyanate function present in the natural product, and also enables synthesis of remarkable bridgehead alkenes.
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Valerie Boissel, Nigel S Simpkins, Gurdip Bhalay, Alexander J Blake, William Lewis. Bridgehead enolates and bridgehead alkenes in a welwistatin model series. Chemical communications (Cambridge, England). 2009 Mar 21(11):1398-400
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PMID: 19259600
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