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Polarized dinitramide anions on the surface of solid ammonium dinitramide (ADN) have a decomposition barrier that is reduced by 16 kcal mol(-1) and explain the anomalous solid state decomposition of ADN.


Martin Rahm, Tore Brinck. The anomalous solid state decomposition of ammonium dinitramide: a matter of surface polarization. Chemical communications (Cambridge, England). 2009 May 28(20):2896-8

PMID: 19436902

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