Unusual quantum interference in the S1 state of DABCO and observation of intramolecular vibrational redistribution.

In this paper we report an experimental study of the time-resolved response of the molecule 1,4-diazabicyclo[2.2.2]octane (DABCO) to 266.3 nm electronic excitation of the S(1) state with a femtosecond laser. Rotational decoherence and vibrational oscillation within the S(1) state are observed. We performed state-of-the-art ab initio calculations on the ground and low electronic states of the neutral molecule and the cation, which assist in the assignment of the observed photoelectron signals. Using our theoretical and spectroscopic data, the experimental findings are interpreted in terms of an unusual quantum interference between two different vibrational modes, with only the nu = 1 level of each mode being populated.

Citation

Lionel Poisson, Raman Maksimenska, Benoît Soep, Jean-Michel Mestdagh, David H Parker, Mama Nsangou, Majdi Hochlaf. Unusual quantum interference in the S1 state of DABCO and observation of intramolecular vibrational redistribution. The journal of physical chemistry. A. 2010 Mar 11;114(9):3313-9

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PMID: 20000592

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