Vanadocene arsenate complexes: evidence of super-hyperfine coupling with (75)As.

Jan Honzícek, Jaromír Vinklárek, Pavel Kratochvíl, Jan Hrbác

Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, 532 10 Pardubice, Czech Republic. jan.honzicek@upce.cz

Magnetic resonance in chemistry : MRC 2010 Jul

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The reaction of vanadocene dichloride with sodium arsenate gives Cp(2)V(O(2)AsO(2)H). This compound was identified on the basis of the super-hyperfine coupling observed in the solution EPR spectrum. The effect of substitution was studied on the ring-substituted and ansa-bridged compounds. Copyright (c) 2010 John Wiley & Sons, Ltd.

Citation

Jan Honzícek, Jaromír Vinklárek, Pavel Kratochvíl, Jan Hrbác. Vanadocene arsenate complexes: evidence of super-hyperfine coupling with (75)As. Magnetic resonance in chemistry : MRC. 2010 Jul;48(7):562-4