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Organolanthanoid-halide synthons--a new general route to monofunctionalized lanthanoid(II) compounds?
Michal Wiecko, Glen B Deacon, Peter C Junk
School of Chemistry, Monash University, Clayton, Victoria 3800, Australia. mwiecko@freenet.de
Chemical communications (Cambridge, England) 2010 Jul 28Sizes of these terms reflect their relevance to your search.
New Eu(II) and Yb(II) complexes [Ln(Ph(2)pz)I(thf)(4)] were synthesized from the corresponding metals and 3,5-diphenylpyrazole (HPh(2)pz) using iodobenzene as oxidizing agent. In the absence of the pyrazole, the charge separated Yb(II)/Yb(III) complex [{Yb(dme)(4)}{YbPh(4)(dme)}(2)] has been isolated.
Citation
Michal Wiecko, Glen B Deacon, Peter C Junk. Organolanthanoid-halide synthons--a new general route to monofunctionalized lanthanoid(II) compounds? Chemical communications (Cambridge, England). 2010 Jul 28;46(28):5076-8
PMID: 20552131
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