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First synthesis of 3-aryl-4-unsubstituted-6-CF(3)-pyridin-2-ones via aryl migration reaction in the presence of PhI(OAc)(2)/NaOH.
Hai Yi, Liping Song, Wei Wang, Jianning Liu, Shizheng Zhu, Hongmei Deng, Min Shao
Department of Chemistry, School of Science, Shanghai University, 99 Shangda Road, Shanghai 200444, PR China.
Chemical communications (Cambridge, England) 2010 Oct 7Sizes of these terms reflect their relevance to your search.
3-Aryl-4-unsubstituted-6-CF(3)-pyridin-2-ones have been efficiently synthesized from readily available 4-aryl-3-carbamoyl-6-CF(3)-pyridin-2(1H)-ones by treatment with PhI(OAc)(2) in the presence of NaOH.
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Hai Yi, Liping Song, Wei Wang, Jianning Liu, Shizheng Zhu, Hongmei Deng, Min Shao. First synthesis of 3-aryl-4-unsubstituted-6-CF(3)-pyridin-2-ones via aryl migration reaction in the presence of PhI(OAc)(2)/NaOH. Chemical communications (Cambridge, England). 2010 Oct 7;46(37):6941-3
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PMID: 20730174
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