Connectivity of PS-b-PEO templated spherical pores in titanium oxide films.

Debraj Chandra, Tatsuki Ohji, Kazumi Kato, Tatsuo Kimura

Advanced Manufacturing Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Shimoshidami, Nagoya 463-8560, Japan.

Physical chemistry chemical physics : PCCP 2011 Jul 21

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Titania films having relatively uniform spherical pores were successfully fabricated using polystyrene-block-poly(ethylene oxide) (PS(n)-b-PEO(m)) diblock copolymers. Depending on the molecular weight of PS(n)-b-PEO(m), the spherical pores were varied from large mesopores (n = 40,000, m = 53,000; ∼40 nm) to macropores (n = 58,600, m = 71,000; ∼60 nm, n = 100,000, m = 150,000; ∼100 nm) in diameter. It was confirmed that the porous structures were thermally stable with crystallization of the titania frameworks. Interconnectivity between the spherical pores was reliant on the micellar arrangement of hydrophobic PS cores, while the amount of isolated pores was increased in the films prepared using low molecular weight PS(n)-b-PEO(m). The presence of such isolated pores was confirmed on the basis of adsorption experiments by using a globular hemoprotein cytochrome c (ca. 3.1 nm). Highly interconnected spherical pores, which were preferentially fabricated using high molecular weight PS(n)-b-PEO(m), were quite helpful for smooth diffusion-adsorption of bulky proteins inside the porous films. This journal is © the Owner Societies 2011

Citation

Debraj Chandra, Tatsuki Ohji, Kazumi Kato, Tatsuo Kimura. Connectivity of PS-b-PEO templated spherical pores in titanium oxide films. Physical chemistry chemical physics : PCCP. 2011 Jul 21;13(27):12529-35