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Hydrogenation of azides over copper nanoparticle surface using ammonium formate in water.
Sabir Ahammed, Amit Saha, Brindaban C Ranu
Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Kolkata-700032, India.
The Journal of organic chemistry 2011 Sep 2Sizes of these terms reflect their relevance to your search.
Aryl azides undergo clean reduction by copper nanoparticles and ammonium formate in water. The surface hydrogen on copper nanoparticles is considered to be the active reducing species. A variety of functionalized aryl azides and aryl sulfonyl azides are reduced by this procedure to the corresponding amines with excellent chemoselectivity in high yields.
Citation
Sabir Ahammed, Amit Saha, Brindaban C Ranu. Hydrogenation of azides over copper nanoparticle surface using ammonium formate in water. The Journal of organic chemistry. 2011 Sep 2;76(17):7235-9
PMID: 21793592
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