First kinetic evidence for the CH/π and π/π solute-solvent interaction of C60 in the Diels-Alder reaction with cyclohexadiene.

Takumi Oshima, Tsubasa Mikie, Naohiko Ikuma, Hajime Yakuma

Graduate School of Engineering, Osaka University, Suita, Osaka, Japan. oshima@chem.eng.osaka-u.ac.jp

Organic & biomolecular chemistry 2012 Mar 7

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The first CH/π solute-solvent interaction of C(60) was evidenced by the kinetic solvent effects in the Diels-Alder reaction with 1,3-cyclohexadiene based on the evaluation of linear free energy relationship of log k(2) with empirical solvent polarity and basicity parameters, E(T)(30) and D(π), respectively.

Citation

Takumi Oshima, Tsubasa Mikie, Naohiko Ikuma, Hajime Yakuma. First kinetic evidence for the CH/π and π/π solute-solvent interaction of C60 in the Diels-Alder reaction with cyclohexadiene. Organic & biomolecular chemistry. 2012 Mar 7;10(9):1730-4