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The metalation of various SEM-protected functionalized indazoles with TMP(2)Zn provides 3-zincated indazoles which undergo palladium-catalyzed Negishi cross-couplings in good yields. This journal is © The Royal Society of Chemistry 2012


Andreas Unsinn, Paul Knochel. Regioselective zincation of indazoles using TMP2Zn and Negishi cross-coupling with aryl and heteroaryl iodides. Chemical communications (Cambridge, England). 2012 Mar 11;48(21):2680-2

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PMID: 22307020

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