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Enantiomeric syntheses of (-)-homopipecolic acid and (-)-pelletierine have been achieved by chiral resolution of tropanol followed by Baeyer-Villiger oxidation. The methodology provides a practical route for the synthesis of optically pure piperidines.

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Wen-Hua Chiou, Guei-Tang Chen, Chien-Lun Kao, Yu-Kai Gao. Syntheses of (-)-pelletierine and (-)-homopipecolic acid. Organic & biomolecular chemistry. 2012 Apr 7;10(13):2518-20

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PMID: 22349358

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