Raman spectroscopic study of the mineral arsenogorceixite BaAl₃AsO₃(OH)(AsO₄,PO₄)(OH,F)₆.

Chemistry Discipline, Faculty of Science and Technology, Queensland University of Technology, GPO Box 2434, Brisbane, Queensland 4001, Australia. r.frost@qut.edu.au

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 2012 Jun

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Arsenogorceixite BaAl(3)AsO(3)(OH)(AsO(4),PO(4))(OH,F)(6) belongs to the crandallite mineral subgroup of the alunite supergroup. Arsenogorceixite forms a continuous series of solid solutions with related minerals including gorceixite, goyazite, arsenogoyazite, plumbogummite and philipsbornite. Two minerals from (a) Germany and (b) from Ashburton Downs, Australia were analysed by Raman spectroscopy. The spectra show some commonality but the intensities of the peaks vary. Sharp intense Raman bands for the German sample, are observed at 972 and 814 cm(-1) attributed to the ν(1) PO(4)(3-) and AsO(4)(3-) symmetric stretching modes. Raman bands at 1014, 1057, 1148 and 1160 cm(-1) are attributed to the ν(1) PO(2) symmetric stretching mode and ν(3) PO(4)(3-) antisymmetric stretching vibrations. Raman bands at 764 and 776 cm(-1) and 758 and 756 cm(-1) are assigned to the ν(3) AsO(4)(3-) antisymmetric stretching vibrations. For the Australian mineral, the ν(1) PO(4)(3-) band is found at 973 cm(-1). The intensity of the arsenate bands observed at 814, 838 and 870 cm(-1) is greatly enhanced. Two low intensity Raman bands at 1307 and 1332 cm(-1) are assigned to hydroxyl deformation modes. The intense Raman band at 441 cm(-1) with a shoulder at 462 cm(-1) is assigned to the ν(2) PO(4)(3-) bending mode. Raman bands at 318 and 340 cm(-1) are attributed to the (AsO(4))(3-)ν(2) bending. The broad band centred at 3301 cm(-1) is assigned to water stretching vibrations and the sharper peak at 3473 cm(-1) is assigned to the OH stretching vibrations. The observation of strong water stretching vibrations brings into question the actual formula of arsenogorceixite. It is proposed the formula is better written as BaAl(3)AsO(3)(OH)(AsO(4),PO(4))(OH,F)(6)·xH(2)O. The observation of both phosphate and arsenate bands provides a clear example of solid solution formation. Copyright © 2012 Elsevier B.V. All rights reserved.

Citation

Ray L Frost, Yunfei Xi, Ross E Pogson. Raman spectroscopic study of the mineral arsenogorceixite BaAl₃AsO₃(OH)(AsO₄,PO₄)(OH,F)₆. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy. 2012 Jun;91:301-6