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Thiopyrimidine pairs in DNA duplexes were unexpectedly largely stabilized by complexation with two equivalents of Ag(I) ions and their binding properties were evaluated. The metal ion-binding properties of the thiopyrimidine base pairs differed significantly from those of unpaired bases.


Itaru Okamoto, Takashi Ono, Rimi Sameshima, Akira Ono. Metal ion-binding properties of DNA duplexes containing thiopyrimidine base pairs. Chemical communications (Cambridge, England). 2012 May 7;48(36):4347-9

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PMID: 22448393

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