Kinetic effects of tartaric acid on the growth of chiral J-aggregates of tetrakis(4-sulfonatophenyl)porphyrin.

Maria Angela Castriciano, Andrea Romeo, Roberto Zagami, Norberto Micali, Luigi Monsù Scolaro

CNR-ISMN, Istituto per lo Studio dei Materiali Nanostrutturati, 98166, V.le F. Stagno D'Alcontres 31, Messina, Italy. castriciano@pa.ismn.cnr.it

Chemical communications (Cambridge, England) 2012 May 18

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The kinetics of growth for chiral J-aggregates of H(4)TPPS(4) porphyrin have been investigated under different experimental conditions in the presence of tartaric acid. The observed rate constants and the anisotropy factor g show a defined dependence on the enantiomer used as a chiral templating agent. This journal is © The Royal Society of Chemistry 2012

Citation

Maria Angela Castriciano, Andrea Romeo, Roberto Zagami, Norberto Micali, Luigi Monsù Scolaro. Kinetic effects of tartaric acid on the growth of chiral J-aggregates of tetrakis(4-sulfonatophenyl)porphyrin. Chemical communications (Cambridge, England). 2012 May 18;48(40):4872-4