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Highly dispersed palladium chloride catalysts locked in triphenylphosphine-functionalized knitting aryl network polymers (KAPs) are developed and exhibit excellent activity under mild conditions in the Suzuki-Miyaura cross-coupling reactions of aryl chlorides in aqueous media. This work highlights that the microporous polymers not only play the role of support materials, but also protect the Pd species from aggregation and precipitation, hence, positively effect the catalysis activity. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.


Buyi Li, Zhenhong Guan, Wei Wang, Xinjia Yang, Jianglin Hu, Bien Tan, Tao Li. Highly dispersed pd catalyst locked in knitting aryl network polymers for Suzuki-Miyaura coupling reactions of aryl chlorides in aqueous media. Advanced materials (Deerfield Beach, Fla.). 2012 Jul 3;24(25):3390-5

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PMID: 22674537

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