Aditi S Patil, Dong-Liang Mo, Heng-Yen Wang, Daniel S Mueller, Laura L Anderson
Department of Chemistry, University of Illinois at Chicago, 845 W. Taylor St. MC 111, Chicago, IL 60613, USA.
Angewandte Chemie (International ed. in English) 2012 Jul 27Two in two: Dioxygenation of alkenyl boronic acids has been achieved with N-hydroxyphthalimide. The two-step process involves etherification of an alkenyl boronic acid with N-hydroxyphthalimide followed by a [3,3] rearrangement. The dioxygenated product can then be hydrolyzed to form either the corresponding α-hydroxy ketone or the α-benzoyloxy ketone. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Aditi S Patil, Dong-Liang Mo, Heng-Yen Wang, Daniel S Mueller, Laura L Anderson. Preparation of α-oxygenated ketones by the dioxygenation of alkenyl boronic acids. Angewandte Chemie (International ed. in English). 2012 Jul 27;51(31):7799-803
PMID: 22744839
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