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The lack of stability of the 9-membered enediynes not associated with an apoprotein may explain the low number of isolated natural compounds containing this core. To overcome such a problem, particular attention should be paid during the process of extraction and isolation of secondary metabolites, especially from microorganisms such as actinomycetes in order to identify the non-cycloaromatized derivatives.


Mickaël Jean, Sophie Tomasi, Pierre van de Weghe. When the nine-membered enediynes play hide and seek. Organic & biomolecular chemistry. 2012 Oct 7;10(37):7453-6

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PMID: 22898710

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