Growth and characterization of Methyl 2-amino-5-bromobenzoate crystal for NLO applications.

M Parthasarathy, R Gopalakrishnan

Crystal Research Lab, Department of Physics, Anna University, Chennai 600 025, India.

Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy 2012 Nov

filter terms:

Good quality single crystal of organic Methyl 2-amino-5-bromobenzoate (M2A5B) was grown using slow evaporation solution growth technique. The grown crystal was confirmed by single crystal X-ray diffraction. The functional groups and vibrational frequencies were identified using FT-IR and FT-Raman spectral analyses. The presence of hydrogen and carbon atoms in the grown sample was confirmed with proton and carbon NMR spectral studies. The optical energy band gap of the title compound is found to be 2.7 eV from the optical transmission spectra. The refractive indices n(x), n(y), and n(z) were found to be 1.569, 1.587 and 1.600, respectively using Brewster's angle method. The melting point of the material obtained with melting point apparatus is 74°C. Thermal stability of the grown crystal was studied by thermogravimetric analysis (TGA) and differential thermal analysis (DTA). The mechanical behaviour of the grown crystal was analyzed with Vicker's microhardness tester. The particle size dependent second harmonic generation efficiency for M2A5B was evaluated by Kurtz-Perry powder method using Nd:YAG laser, which established the existence of phase matching. Copyright © 2012 Elsevier B.V. All rights reserved.

Citation

M Parthasarathy, R Gopalakrishnan. Growth and characterization of Methyl 2-amino-5-bromobenzoate crystal for NLO applications. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy. 2012 Nov;97:1152-8