Fe(CO)3}4{SnI}6I4]2-: the first bimetallic adamantane-like cluster.

Silke Wolf, Florian Winter, Rainer Pöttgen, Nils Middendorf, Wim Klopper, Claus Feldmann

Institut für Anorganische Chemie, Karlsruhe Institute of Technology, Germany.

Chemistry (Weinheim an der Bergstrasse, Germany) 2012 Oct 22

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Show some metal: the first bimetallic adamantane-like cluster, [{Fe(CO)(3)}(4){SnI}(6)I(4)](2-), was prepared by an ionic-liquid-based synthesis. The valence states of iron and tin were verified based on bond-length considerations, FT-IR and (119)Sn Mössbauer spectroscopy, as well as with DFT calculations. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Citation

Silke Wolf, Florian Winter, Rainer Pöttgen, Nils Middendorf, Wim Klopper, Claus Feldmann. Fe(CO)3}4{SnI}6I4]2-: the first bimetallic adamantane-like cluster. Chemistry (Weinheim an der Bergstrasse, Germany). 2012 Oct 22;18(43):13600-4