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The challenging coupling of 10-halobenzo[h]quinolines with ortho-substituted aryl boronic acids has been achieved using Pd(OAc)(2)/P(O)Ph(3) as the catalytic system. High yields were obtained for diversely functionalised substrates under mild reaction conditions.


Marko Weimar, Matthew J Fuchter. Synthesis of sterically encumbered C10-arylated benzo[h]quinolines using ortho-substituted aryl boronic acids. Organic & biomolecular chemistry. 2013 Jan 7;11(1):31-4

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PMID: 23069777

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