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An easily available Pd(OAc)(2)/(2-mesitylindenyl)dicyclohexylphosphine/Me(octyl)(3)N(+)Cl(-)/K(3)PO(4)ยท3H(2)O catalytic system was developed and it shows high catalytic activity in the Suzuki-Miyaura cross-coupling reaction of a diverse array of aryl and heteroaryl chlorides in water. Notably, this catalytic system also works with ultra-low loading of the catalyst with high turnover numbers.


Shu-Lan Mao, Yue Sun, Guang-Ao Yu, Cui Zhao, Zhi-Jun Han, Jia Yuan, Xiaolei Zhu, Qihua Yang, Sheng-Hua Liu. A highly active catalytic system for Suzuki-Miyaura cross-coupling reactions of aryl and heteroaryl chlorides in water. Organic & biomolecular chemistry. 2012 Dec 21;10(47):9410-7

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PMID: 23111458

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