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For the first time a metal hydride has been used for the preparation of a metal-organic framework. MIL-78 has been synthesized by the solid-state mechanochemical reaction between yttrium hydride and trimesic acid. The process does not involve solvents and does not generate liquid by-products, thus proving the viability of the solid-state approach to the synthesis of MOFs.

Citation

Niraj K Singh, Meenakshi Hardi, Viktor P Balema. Mechanochemical synthesis of an yttrium based metal-organic framework. Chemical communications (Cambridge, England). 2013 Feb 1;49(10):972-4

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PMID: 23128845

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