Dichlorido{2-[(2,6-diethylphenyl)iminomethyl]quinoline-κ2N,N'}palladium(II) acetonitrile monosolvate.

William M Motswainyana, Martin O Onani, Jeroen Jacobs, Luc Van Meervelt

Chemistry Department, University of the Western Cape, Bellville, South Africa.

Acta crystallographica. Section C, Crystal structure communications 2012 Dec

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The title complex, [PdCl(2)(C(20)H(20)N(2))]·CH(3)CN, was synthesized by the reaction of 2-[(2,6-diethylphenyl)iminomethyl]quinoline with dichlorido(cycloocta-1,5-diene)palladium(II) in dry CH(2)Cl(2). The Pd(II) ion is coordinated by two N atoms of the bidentate quinoline ligand and by two chloride anions, generating a distorted square-planar coordination geometry around the metal centre. There is a detectable trans influence for the chloride ligands. The crystal packing is characterized by π-π stacking between the quinoline rings. The use of acetonitrile as the crystallization solvent was essential for obtaining good-quality crystals.

Citation

William M Motswainyana, Martin O Onani, Jeroen Jacobs, Luc Van Meervelt. Dichlorido{2-[(2,6-diethylphenyl)iminomethyl]quinoline-κ2N,N'}palladium(II) acetonitrile monosolvate. Acta crystallographica. Section C, Crystal structure communications. 2012 Dec;68(Pt 12):m356-8