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Catalytic highly enantioselective vinylogous Povarov reaction.

Lorenzo Caruana, Mariafrancesca Fochi, Silvia Ranieri, Andrea Mazzanti, Luca Bernardi

Department of Industrial Chemistry Toso Montanari, School of Science, University of Bologna, V. Risorgimento 4, 40136 Bologna, Italy.

Chemical communications (Cambridge, England) 2013 Jan 30


filter terms:
  • 1 2, 3, 4- tetrahydroquinoline (2)
  • butadienes (3)
  • catalysis (1)
  • phosphoric acid (4)
  • quinolines (2)
  • stereoisomerism (1)
    • Sizes of these terms reflect their relevance to your search.

    The first example of a catalytic asymmetric vinylogous Povarov reaction is presented. 1-N-Acylamino-1,3-butadienes react selectively at their terminal double bond in the presence of a chiral phosphoric acid catalyst, delivering highly enantioenriched 1,2,3,4-tetrahydroquinolines bearing a synthetically versatile enecarbamate group at the 4-position.

    Citation

    Lorenzo Caruana, Mariafrancesca Fochi, Silvia Ranieri, Andrea Mazzanti, Luca Bernardi. Catalytic highly enantioselective vinylogous Povarov reaction. Chemical communications (Cambridge, England). 2013 Jan 30;49(9):880-2

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    PMID: 23238127

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