Sustainable high capacitance at high frequencies: metallic aluminum-polypropylene nanocomposites.

The high-frequency dielectric response of 0-3 polypropylene nanocomposites prepared with the activated metallocene polymerization catalyst [rac-ethylenebisindenyl]zirconium dichlororide absorbed on the native Al(2)O(3) surfaces of metallic aluminum nanoparticles is characterized. The nanocomposites produced are randomly dispersed in the polyolefin matrix with no visible defects that might degrade film dielectric properties. Electrical measurements show that as the volume fraction of Al nanoparticles is increased, the effective permittivity of the nanocomposites increases, with ε(r) values reaching ~10 at relatively low frequency (1 MHz). Because of the high permittivity and conductivity contrast between the metal nanoparticles and the polypropylene matrix, Maxwell-Wagner-Sillars theory can be applied to model the loss at high frequencies and provide insight into how the nanocomposite high frequency response scales with Al volume fraction. At higher Al nanoparticle volume fractions, mixing theories predict greater densities of nanoparticle aggregates, consistent with the experimentally observed shift of the dielectric relaxation to lower frequencies. Although these nanocomposites undergo the predicted initial dielectric relaxation with increasing frequency, the metallic nanoparticle complex permittivity imbues the higher Al volume fraction materials with relatively high, sustainable permittivities, 6, at frequencies as high as 7 GHz.

Citation

Lisa A Fredin, Zhong Li, Michael T Lanagan, Mark A Ratner, Tobin J Marks. Sustainable high capacitance at high frequencies: metallic aluminum-polypropylene nanocomposites. ACS nano. 2013 Jan 22;7(1):396-407

Mesh Tags

Substances

PMID: 23259679

search → result