Ag/AgBr/Co-Ni-NO3 layered double hydroxide nanocomposites with highly adsorptive and photocatalytic properties.

Hai Fan, Jianying Zhu, Jianchao Sun, Shenxiang Zhang, Shiyun Ai

College of Chemistry and Material Science, Shandong Agriculture University, Taian, 271018, Shandong, PR China.

Chemistry (Weinheim an der Bergstrasse, Germany) 2013 Feb 11

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A facile anion-exchange precipitation method was used to synthesize bifunctional Ag/AgBr/Co-Ni-NO(3) layered double hydroxide (LDH) nanocomposites by adding AgNO(3) solution to a suspension of Co-Ni-Br LDH. The Ag/AgBr nanoparticles were highly dispersed on the sheets of Co-Ni-NO(3) LDH. The prepared nanocomposites were used to adsorb and photocatalytically degrade organic pollutants from water. Without light illumination, the nanocomposites quickly adsorbed methyl orange, and the adsorptive capacity, which can reach 230 mg g(-1), is much higher than those of Co-Ni-Br LDH, Ag/AgBr, and activated carbon. The photocatalytic activities of the nanocomposites for the removal of dyes and phenol are higher than those of Co-Ni-Br LDH and Ag/AgBr. The proposed method can be applied to prepare other LDH/silver salt composites. The high absorptive capacity and good photocatalytic activity of such nanostructures could have wide applications in wastewater treatment. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Citation

Hai Fan, Jianying Zhu, Jianchao Sun, Shenxiang Zhang, Shiyun Ai. Ag/AgBr/Co-Ni-NO3 layered double hydroxide nanocomposites with highly adsorptive and photocatalytic properties. Chemistry (Weinheim an der Bergstrasse, Germany). 2013 Feb 11;19(7):2523-30