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A V(III) thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a V(III)-Cl species (major one) and a V(IV) binding to a CH(2) containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.


Tzu-Tso Chen, Yu-Sen Chen, Ya-Ho Chang, Jung-Ching Wang, Yi-Fang Tsai, Gene-Hsiang Lee, Tin-Shen Kuo, Hua-Fen Hsu. Activation of dichloromethane by a V(III) thiolate complex: an example of S-based nucleophilic reactivity in an early transition metal thiolate. Chemical communications (Cambridge, England). 2013 Feb 4;49(11):1109-11

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PMID: 23282950

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