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The divergent gold-catalysed reactivity (C(sp(2))-H versus C(sp(3))-H) of aryloxy-tethered allenes has been uncovered.


Benito Alcaide, Pedro Almendros, Sara Cembellín, Teresa Martínez del Campo, Israel Fernández. Gold-catalysed tuning of reactivity in allenes: 9-endo hydroarylation versus formal 5-exo hydroalkylation. Chemical communications (Cambridge, England). 2013 Feb 14;49(13):1282-4

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PMID: 23295954

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