Biological N removal from wastes generated from amine-based CO2 capture: case monoethanolamine.

Ingrid Hauser, Ana B Colaço, Julie A Skjæran, Aslak Einbu, Kjetill Ostgaard, Hallvard F Svendsen, Francisco J Cervantes

Department of Biotechnology, Norwegian University of Science and Technology (NTNU), 7491, Trondheim, Norway. ingrid.hauser@ntnu.no

Applied biochemistry and biotechnology 2013 Feb

filter terms:

Large-scale amine-based CO(2) capture will generate waste containing large amounts of ammonia, in addition to contaminants such as the actual amine as well as degradation products thereof. Monoethanolamine (MEA) has been a dominant amine applied so far in this context. This study reveals how biological N removal can be achieved even in systems heavily contaminated by MEA in post- as well as pre-denitrification treatment systems, elucidating the rate-limiting factors of nitrification as well as aerobic and denitrifying biodegradation of MEA. The hydrolysis of MEA to ammonia readily occurred both in post- and pre-denitrification treatment systems with a hydraulic retention time of 7 h. MEA removal was ≥99 ± 1 % and total nitrogen removal 77 ± 10 % in both treatment systems. This study clearly demonstrates the advantage of pre-denitrification over post-denitrification for achieving biological nitrogen removal from MEA-contaminated effluents. Besides the removal of MEA, the removal efficiency of total nitrogen as well as organic matter was high without additional carbon source supplied.

Citation

Ingrid Hauser, Ana B Colaço, Julie A Skjæran, Aslak Einbu, Kjetill Ostgaard, Hallvard F Svendsen, Francisco J Cervantes. Biological N removal from wastes generated from amine-based CO2 capture: case monoethanolamine. Applied biochemistry and biotechnology. 2013 Feb;169(4):1449-58