Electrochemical polymerization of allylamine copolymers.

Luca Bardini, Marcel Ceccato, Mogens Hinge, Steen U Pedersen, Kim Daasbjerg, Massimo Marcaccio, Francesco Paolucci

G. Ciamician Chemistry Department, University of Bologna, via Selmi 2, 40126 Bologna, Italy. luca.bardini@unibo.it

Langmuir : the ACS journal of surfaces and colloids 2013 Mar 19

filter terms:

We describe for the first time the electro-oxidative synthesis and passivating properties of surface films of poly(allylamine) and copolymers of allylamine and diallylamine. Cyclic voltammetry and impedance spectra show that the films exhibit high charge-transfer resistance and that the addition of diallylamine causes improvements in the compactness and stability toward swelling of the films when compared to both allylamine and diallyamine, leading to coatings with high charge-transfer resistance up to 70 MΩ. We also show that removing oxygen before the polymerization further improves the films' passivating properties.

Citation

Luca Bardini, Marcel Ceccato, Mogens Hinge, Steen U Pedersen, Kim Daasbjerg, Massimo Marcaccio, Francesco Paolucci. Electrochemical polymerization of allylamine copolymers. Langmuir : the ACS journal of surfaces and colloids. 2013 Mar 19;29(11):3791-6