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A chiral supramolecular alternate block copolymer has been self-assembled from a ureidopyrimidinone (UPy)-terminated arylamide-based hydrogen bonded foldamer and a structurally flexible pentamer, which is driven by the ion-pair binding of the two arylamide segments toward chiral ammonium and carboxylate guests.

Citation

Zhu-Ming Shi, Chun-Fang Wu, Tian-You Zhou, Dan-Wei Zhang, Xin Zhao, Zhan-Ting Li. Foldamer-based chiral supramolecular alternate block copolymers tuned by ion-pair binding. Chemical communications (Cambridge, England). 2013 Apr 4;49(26):2673-5

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PMID: 23435527

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