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Remarkable effect of CF3CH2OH for the halogen induced oxidative rearrangement reaction of aminals leading to 3,4-dihydroquinazolines.
Kenichi Murai, Masato Shimura, Ryu Nagao, Daisuke Endo, Hiromichi Fujioka
Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamada-oka, Suita, Osaka 565-0871, Japan.
Organic & biomolecular chemistry 2013 Apr 28Sizes of these terms reflect their relevance to your search.
CF3CH2OH was found to be a useful solvent for the oxidative rearrangement reactions of aminals promoted by N-chlorosuccinimide, which proceed via the intermediacy of in situ formed chloro-aminals and that produce 3,4-dihydroquinazolines.
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Kenichi Murai, Masato Shimura, Ryu Nagao, Daisuke Endo, Hiromichi Fujioka. Remarkable effect of CF3CH2OH for the halogen induced oxidative rearrangement reaction of aminals leading to 3,4-dihydroquinazolines. Organic & biomolecular chemistry. 2013 Apr 28;11(16):2648-51
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PMID: 23460111
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