Bastien Chatelet, Lionel Joucla, Jean-Pierre Dutasta, Alexandre Martinez, Kai C Szeto, Véronique Dufaud
École Normale Supérieure de Lyon, CNRS, Université de Lyon, Laboratoire de Chimie, 46 allée d'Italie, 69364 Lyon, France.
Journal of the American Chemical Society 2013 Apr 10Three azaphosphatranes were used as organocatalysts for the synthesis of cyclic carbonates from CO2 and epoxides. They proved to be efficient single-component, metal-free catalysts for the reaction of simple or activated epoxides (styrene oxide, epichlorohydrin, glycidyl methyl ether) with CO2 under mild reaction conditions, displaying high stability and productivity over several days of reaction. Substitution patterns on the catalyst were shown to affect activity and stability. Kinetic analysis allowed investigation of the reaction mechanism.
Bastien Chatelet, Lionel Joucla, Jean-Pierre Dutasta, Alexandre Martinez, Kai C Szeto, Véronique Dufaud. Azaphosphatranes as structurally tunable organocatalysts for carbonate synthesis from CO2 and epoxides. Journal of the American Chemical Society. 2013 Apr 10;135(14):5348-51
PMID: 23528185
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