Weakly ordered chiral alignment medium derived from 5'-GMP : guanosine.

Lokesh, N Suryaprakash

NMR Research Centre, Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore-560012, India.

Chemical communications (Cambridge, England) 2013 Mar 11

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A novel weakly ordered chiral lyotropic alignment medium, derived by the self-assembly of guanosine 5'-monophosphate (5'-GMP):guanosine for scaling RDCs to desired strengths and for the discrimination of enantiomers, is reported. The preparation of this inexpensive mesophase is straightforward, requires less time (1 h), and is sustainable, reversible and tunable over a wide range of temperature (280-330 K) and concentration.

Citation

Lokesh, N Suryaprakash. Weakly ordered chiral alignment medium derived from 5'-GMP : guanosine. Chemical communications (Cambridge, England). 2013 Mar 11;49(20):2049-51